write the electronic configuration of chromium and predict its number of subshelss,number of eletrons in subshell having l=0,number of electrons having n+l value=3,number of electrons in higest value of n.
Asked by mehrarora26
| 22nd Jul, 2015,
10:36: AM
The electron configuration for chromium is 1s22s22p63s23p64s23d4.
However, in the case of chromium there is one empty d sub orbital, one of the electrons from the 4s orbital will move up to the 3d orbital and make the the actual electron configuration 1s22s22p63s23p64s13d5.
Therefore,
Predicted electron configurations: Cr (Z = 24): [Ar] 4s2 3d4
Actual electron configurations: Cr (Z = 24): [Ar] 4s1 3d5
Quantum number for chromium
n
ℓ
m ℓ
Orbitals
Elements
Shell
n=1
0
0
1s
2
K
n=2
0
0
2s
2 8
6
L
1
-1, 0, 1
2p
n=3
0
0
3s
2
6 13
5
M
1
-1, 0, 1
3p
2
-2, -1, 0, 1, 2
3d
n=4
0
0
4s
1 1
N
1
-1, 0, 1
4p
2
-2, -1, 0, 1, 2
4d
3
-3, -2, -1, 0, 1, 2, 3
4f
(From the above table, we get,)
Predict its number of subshells
Ans: Chromium has 10 subshells viz - 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f
Number of electrons in subshell having l=0
Ans: There are 4 subshells and the first three sub shells (n=1, n=2 and n=3) has 2 electrons each and (n=4) has 1 electron.
Number of electrons having n + ℓ value=3
Ans: Total 8 electrons has n + ℓ value=3.
Number of electrons in highest value of n
Ans: Highest value is the last orbital (N orbital); n=4 i.e, 1 electron.
The electron configuration for chromium is 1s22s22p63s23p64s23d4.
However, in the case of chromium there is one empty d sub orbital, one of the electrons from the 4s orbital will move up to the 3d orbital and make the the actual electron configuration 1s22s22p63s23p64s13d5.
Therefore,
Predicted electron configurations: Cr (Z = 24): [Ar] 4s2 3d4
Actual electron configurations: Cr (Z = 24): [Ar] 4s1 3d5
Quantum number for chromium
n |
ℓ |
m ℓ |
Orbitals |
Elements |
Shell |
n=1 |
0 |
0 |
1s |
2 |
K |
n=2 |
0 |
0 |
2s |
2 8 6 |
L |
1 |
-1, 0, 1 |
2p |
|||
n=3 |
0 |
0 |
3s |
2 6 13 5 |
M |
1 |
-1, 0, 1 |
3p |
|||
2 |
-2, -1, 0, 1, 2 |
3d |
|||
n=4 |
0 |
0 |
4s |
1 1 |
N |
1 |
-1, 0, 1 |
4p |
|
||
2 |
-2, -1, 0, 1, 2 |
4d |
|
||
3 |
-3, -2, -1, 0, 1, 2, 3 |
4f |
|
(From the above table, we get,)
Predict its number of subshells
Ans: Chromium has 10 subshells viz - 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p, 4d, 4f
Number of electrons in subshell having l=0
Ans: There are 4 subshells and the first three sub shells (n=1, n=2 and n=3) has 2 electrons each and (n=4) has 1 electron.
Number of electrons having n + ℓ value=3
Ans: Total 8 electrons has n + ℓ value=3.
Number of electrons in highest value of n
Ans: Highest value is the last orbital (N orbital); n=4 i.e, 1 electron.
Answered by Hanisha Vyas
| 22nd Jul, 2015,
07:35: PM
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