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CBSE Class 12-science Answered

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Asked by Balbir | 02 Oct, 2019, 12:29: AM
answered-by-expert Expert Answer
EMF of cell can be calculated by Nernst equation for the following reactions.
Ag left parenthesis NH subscript 3 right parenthesis subscript 2 to the power of plus space space space space end exponent plus straight e to the power of minus space left right double arrow space Ag space plus 2 NH subscript 3
After space applying space Nernst space equation minus
0.799 equals straight E to the power of straight o minus.0591 cross times log space straight K subscript ins left square bracket Ag left parenthesis NH subscript 3 right parenthesis subscript 2 to the power of plus space space end exponent right square bracket
0.799 equals straight E to the power of straight o minus.0591 cross times log space left parenthesis 6.02 cross times 10 to the power of negative 8 end exponent right parenthesis
0.799 space equals straight E to the power of straight o minus left parenthesis 0.799 minus 8 right parenthesis cross times 0.0591
space 0.799 equals straight E to the power of straight o minus left parenthesis negative 7.201 cross times 0.0591 right parenthesis
straight E to the power of straight o space equals 0.799 minus 0.4255
space space space space space equals 0.372 straight V
In space second space chemical space equation minus
Ag left parenthesis CN right parenthesis subscript 2 to the power of minus space plus space straight e to the power of minus space left right double arrow space Ag plus space 2 CN to the power of minus
After space applying space Nernst space equation minus
0.799 equals straight E to the power of straight o minus.0591 cross times log space straight K subscript ins left square bracket Ag left parenthesis CN right parenthesis subscript 2 to the power of minus right square bracket
0.799 equals straight E to the power of straight o minus space.0591 cross times log left parenthesis 1.99 cross times 10 to the power of negative 19 end exponent right parenthesis
0.799 equals straight E to the power of straight o minus.0591 cross times left square bracket log 1.995 minus 19 log 10 right square bracket
straight E to the power of straight o equals 0.799 minus 1.10517
space space space equals negative 0.307 straight V
Answered by | 03 Oct, 2019, 02:47: PM
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