CBSE Class 11-science Answered
CastnerKellner cell |
Downs cell |
The CastnerKellner cell is an electrolytic cell used industrially for the production of sodium hydroxide. |
The Downs cell is used for the commercial preparation of metallic sodium, in which molten NaCl is electrolyzed. |
These cells are of two types. The first type uses an electrolyte of sodium chloride solution, a graphite anode, and a mercury cathode. The other type of cell uses an electrolyte of sodium hydroxide solution, a mercury cathode, and an iron anode. |
The Downs cell uses a carbon anode and iron cathode. |
A saturated brine solution floats on top of the cathode which is a thin layer of mercury. Chlorine is produced at the anode, and sodium is produced at the cathode where it forms a sodium-mercury amalgam with the mercury. |
The Downs cell has a central graphite anode surrounded by a cylindrical steel cathode. Chlorine gas produced at the anode is led away through a hood, over the anode. Molten sodium is formed at the cathode and collected through another hood around the top of the cathode cylinder
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