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ICSE Class 10 Answered

how to solve numericals on empirical formula and avogadro's law
Asked by aa26 | 27 Jan, 2019, 12:51: PM
answered-by-expert Expert Answer
  • One mole is the amount of a substance that contains as many particles or entities as there are atoms in exactly 12 g (or 0.012 kg) of 12C.
  • Following relations have given below can be summarized as
    • One mole of atoms =  atoms = Gram atomic mass of an element.
    • One mole of molecules =  molecules = Gram molecular mass of a substance.
  • The concentration of a solution can be expressed in any of the following ways: Mass percent, mole fraction, molarity and molality.
  • Molarity is the number of moles of solute in per liter of solution. The unit is moles per liter.

 

  • Molality is the number of moles of solute present in 1 kg of solvent.

 

  • A molecular formula shows the exact number of different types of atoms present in a molecule of a compound.
  • If the mass percent of various elements present in a compound is known, then its empirical formula can be determined.
  • Where, n is a simple number and may have values 1, 2, 3….
  • Following steps should be followed to determine the empirical formula of the compound:
    • Step 1: Conversion of mass percent of various elements into grams.
    • Step 2: Convert mass obtained in step 1 into the number of moles.
    • Step 3: Divide the mole value obtained in step 2 by the smallest mole value (out of the mole value of various elements calculated).
    • Step 4: In case the ratios are not whole numbers, they may be converted into whole numbers by multiplying by a suitable coefficient.
    • Step 5: Write the empirical formula by mentioning the numbers after writing the symbols of respective elements.'
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