CBSE Class 12-science Answered
Nitroethane and Ethyl nitrite have same chemical formulae. But What is difference between them? Do they show same chemical properties?
Asked by shrikrushna deokar | 26 Nov, 2013, 04:07: PM
Expert Answer
Boiling Point:
Boiling point of ethyl nitrite is 170C
Boiling point of Nitroethane is 1150C.
Reduction with metal and acid:
Ethyl nitrite gives alcohol+ hydroxyl amine or NH3
C2H5ONO + 4H → C2H5OH + NH2OH
Nitroethane gives corresponding primary amine.
C2H5NO2 + 6H → C2H5NH2 + 2H2O
Action on NaOH:
Ethyl nitrite is readily hydrolysed to give corresponding alcohol and sodium nitrite.
C2H5ONO + NaOH → C2H5OH + NaNO2
Nitroethane is not decomposed and alcohols are not formed.
Action on nitrous acid:
Nitrous acid has no action ethyl nitrite.
Nitro ethane when reacts with nitrous acid forms nitrolic acid which dissolves in alkali to give red solution.
Answered by Karishma Kapoor | 27 Nov, 2013, 03:06: PM
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