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  How many gram of KmO_4 should be taken to make up 250 ml of a solution of such strength that 1ml is equivalent to 5Mg of Fe in  a) 1.414g b) 0.70g c) 3.16g d) 1.58g  
Asked by Ranjeetgupta26068 | 21 May, 2019, 08:07: AM
answered-by-expert Expert Answer
Option (b) will be right when the unit is given in kiligram.
 
We know,
 
MnO subscript 4 to the power of minus space rightwards arrow space Mn to the power of 2 plus end exponent
space plus 7 space space space space space space space space space space plus 2

Change space in space oxidation space number space equals space 5

Fe to the power of 2 plus end exponent space rightwards arrow space Fe to the power of 3 plus end exponent
plus 2 space space space space space space space space plus 3

Change space in space oxidation space number space equals space 1

Therfore semicolon
Equivalent space weight space of space KMnO subscript 4 space equals space straight M over 5

Equivalent space weight space of space Fe space equals fraction numerator space straight M over denominator 1 end fraction

straight M. space equ space of space Fe space equals space 5 over 56

1 space ml space of space straight f space KMnO subscript 4 space contains space 5 over 56 space straight M space equ space of space straight f space KMnO subscript 4

250 space ml space of space straight M space equ space of space straight f space KMnO subscript 4 space will space conatain space space 5 over 56 cross times 250 space Mequ space of space KMnO subscript 4

We space know comma

Mequ space of space KMnO subscript 4 space equals space fraction numerator Weight space in space mg over denominator Equivalent space weight space in space mg end fraction

therefore Weight space in space mg space equals space Mequ space of space KMnO subscript 4 space cross times Equivalent space weight space in space mg

Equivalent space weight space of space space KMnO subscript 4 space in space mg space equals space fraction numerator Molecular space weight space over denominator Change space in space oxidation space no. end fraction

space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals space 158 over 5 space equals space 31.6 space gm

Equivalent space weight space of space space KMnO subscript 4 space in space mg space equals space 31.6 space cross times 10 cubed space mg

Weight space of space KMnO subscript 4 space in space mg space equals space 5 over 56 cross times 250 cross times space 31.6 space cross times 10 cubed

space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals space 705.35 space cross times 10 cubed space mg

space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals space 705 space gm

Weight space of space KMnO subscript 4 space in space mg space equals 0.7 space kg
 
The weight of KMnO4 required is 705 gm or 0.7 kg
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