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CBSE Class 11-science Answered

how is cfc responsible for depletion of ozone layer?
Asked by Badrinath Mishra | 09 Feb, 2013, 10:42: PM
answered-by-expert Expert Answer

Ozone in the lower atmosphere is formed during electrical discharge from high voltage appliances as shown in the equations below:

 

O2(g) -----> 2O(g)

O2(g) + O(g) -----> O3(g)

CFCs destroy the ozone in the stratosphere (15 - 20 km above the earth's surface)
(Ozone concentrations are measure in Dobsen units, 1 Dobsen unit represents 1 molecule of O3 for every 1 billion air molecules)
Ozone loss is greatest over Antarctica where the ozone depletion has been recorded and is commonly referred to as the "ozone hole".
 
  • In the stratosphere, CFCs come into contact with short wavelength ultraviolet radiation which is able to split off chlorine atoms from the CFC molecules
CCl3F(g) u.v radiation
--------------->
CCl2F(g) + Cl(g)

     

  • These chlorine atoms destroy the ozone layer
Cl(g) + O3(g) -------------> ClO(g) + O2(g)

     

  • There are significant numbers of oxygen atoms in the stratosphere (since ozone undergoes a natural photochemical decomposition producing oxygen atoms and molecules) which leads to the regeneration of chlorine atoms in the stratosphere.
    So, 1 CFC molecule can destroy many ozone molecules.
ClO(g) + O(g) -------------> O2(g) + Cl(g)


Answered by | 10 Feb, 2013, 10:18: AM
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