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CBSE Class 11-science Answered

Discuss resonance in benzene.
Asked by Topperlearning User | 01 Jun, 2016, 02:41: PM
answered-by-expert Expert Answer

  • The phenomenon in which two or more equivalent  structures for a compound can be written which involve identical positions of atoms but differ in the arrangements of electrons is called resonance and the structures are called resonating structures.
  • The structure of molecule is said to be a hybrid structure of various resonating structures and is known as resonance hybrid.
  • Carbon carbon bonds in benzene are equivalent having bond length 1.40A which is intermediate between the lengths of carbon single bond and carbon carbon double bond.
  • The structure of  benzene is a hybrid of various resonating structures.
  • The  two structures (A) and (B) given by Kekule are main contributing structures.
  • The hybrid structure is represented by inserting a circle or a dotted circle in hexagon as shown in (C) and (D).
  • The circle represents the six electrons which are delocalised over the six carbon atoms of the benzene ring.

 

 

                    

Answered by | 01 Jun, 2016, 04:41: PM
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