Question Paper (Section wise)

1) Surface of certain metal is first illuminated with light of wavelength Î»_{1 }= 350 nm and then, the light of wavelength Î»_{2 }= 540 nm. It is found that the maximum speed of the photo electrons in the two cases differ by a factor of 2. The work function of the metal (in eV) is close to:

1.8

2.5

5.6

1.4


2) A sample of radioactive material A, that has an activity of 10mCi (1 Ci = 3.7 Ã— 10^{10 }decays/s), has twice the number of nuclei as another sample of different radioactive material B which has an activity of 20mCi. The correct choice for halflives of A and B would then be respectively:

5 days and 10 days

10 days 40 days

20 days 5 days

20 days 10 days


3) Three blocks A, B and C are lying in a smooth horizontal surface, as shown in the figure. A and B have equal masses, m while C has mass M. Block A is given an initial speed v towards B due to which it collides with B perfectly inelastically. The combined mass collides with C, also perfectly inelastically. The combined mass collides with C, also perfectly inelastically if Â th of the initial kinetic energy is lost in whole process. What is value of M/m?

5

2

4

3


4) A metal plate of area 1 × 10^{4 }m^{2} is illuminated by a radiation of intensity 16 mW/m^{2}. The work function of the metal is 5 eV. The energy of the incident photons is 10 eV and only 10 % of it produces photo electrons. The number of emitted photo electrons per second and their maximum energy, respectively, will be:
[1eV = 1.6 ×10^{19}J]

10^{14 }and 10 eV

10^{12} and 5 eV

10^{11} and 5 eV

10^{10} and 5 eV


5) The modulation frequency of an AM radio station is 250 kHz, which is 10% of the carrier wave. If another AM station approaches you for license what broadcast frequency will you allot?

2750kHz

2900kHz

2250 kHz

2000kHz


6) Two force P and Q, of magnitude 2F and 3F, respectively, are at an angle Î¸ with each other. If the force Q is doubled, then resultant also doubled. Then, the angle Î¸ is:

120Â°

60Â°

90Â°

30Â°


7) In a Youngâ€™s double slit experiment, the path difference, at a certain point on the screen, between two interfering waves is 1/8^{th} of wavelength. The ratio of the intensity at this point to that at the Centre of a bright fringe is close to:

0.74

0.85

0.94

0.80


8) A slab is subjected to the two forces Â and of same magnitude F as shown in the figure. Force Â is in XY â€“plane while force F_{1} acts along Z axis at the point. The moment of these forces about point O will be:


9) In a Wheatstone bridge (see figure) Resistance P and Q are approximately equal. When R = 400 Î©, the bridge is balanced. On interchanging P and Q, the value of R, for balance is 405 Î©. The value of X is close to:

401.5 ohm

404.5 ohm

403.5 ohm

402.5 ohm


10) In the above circuit,.
Current in LR_{1} path is I_{1} and C R_{2} path is I_{2}. The voltage of A. C. source is given by, volts.
The phase difference between I_{1} and I_{2} is:

60Â°

30Â°

90Â°

150Â°


11) A galvanometer, whose resistance is 50 ohm, has 25 divisions in it. When a current of 4 Ã— 10^{4} A passes through it, its needle (pointer) deflects by one division. To use this galvanometer as a voltmeter of range 2.5 V, it should be connected to a resistance of:

250 ohm

200 ohm

6200 ohm

6250 ohm


12) The charge on a capacitor plate in a circuit, as a function of time, is shown in the figure:
What is the value of current at t = 4 s?

Zero

3 ÂµA

2 ÂµA

1.5 ÂµA


13) Youngâ€™s moduli of two wires A and B are in the ration 7:4 Wire A is 2 m long and has radius R. Wire A is 2 m long and has radius r. Wire B is 1.5 m long and has radius 2 mm. If the two wires stretch by the same length for a given load, then the value of R is closed to:

1.3 mm

1.5 mm

1.7 mm

1.9 mm


14) A body of mass m_{1} moving with an unknown velocity of undergoes a collinear collision with a body of mass m_{2} moving with a velocity After collision m_{1} and m_{2} move with velocities of and respectively.



V_{4} – V_{2}

V_{4} + V_{2}


15) A rocket has to be launched from each in such a way that it never returns. If E is the minimum energy delivered by the rocket launcher, what should be the minimum energy that the launcher should have if the same rocket is to be launched form the surface of the moon? Assume that the density of the earth and the moon are equal and that the earthâ€™s volume is 64 times the volume of the moon.


16) The total number of turns and crosssection area in solenoid is fixed. However, its length L is varied by adjusting the separation between windings. The inductance of solenoid will be proportional to:

1/L

L

1/L^{2}

L^{2}


17) Determine the charge on the capacitor in the following circuit:

200Î¼C

60Î¼C

10Î¼C

2Î¼C


18) A rigid square loop of side â€˜aâ€™ and carrying current I_{2} is laying on a horizontal surface near a long current I_{1} wire in the same plane as shown in figure. The net force on the loop due to the wire will be:

Repulsive and equal to

Attractive and equal to

Zero

Repulsive and equal to


19) The elastic limit of brass is 379 MPa. What should be the minimum diameter of a brass rod if it is to support a 400 N load without exceeding its elastic limit?

1.00 mm

1.16 mm

0.90 mm

1.36 mm


20) Water from a tap emerges vertically downwards with an initial speed of 1.0 ms^{1}. The crosssectional area of the tap is 10^{4}m^{2}. Assume that the pressure is constant throughout the stream of water and that flow is streamlined. The crosssectional area of the stream, 0.15 m below the tap would be:
(Take, g = 110 ms^{2})

5 Ã— 10^{4} m^{2}

5 Ã— 10^{5} m^{2}

1 Ã— 10^{5} m^{2}

2 Ã— 10^{5} m^{2}


21) A cubical block of side 0.5 m floats on water with 30% of its volume under water. What is the maximum weight (kg) that can be put on the block without fully submerging it under water?
[Take density of water = 10^{3} kg/m^{3}]

22) The stopping potential V_{0} (in volt) as a function of frequency (Î½) for a sodium emitter, is shown in the figure. The approximate work function of sodium, from the data plotted in the figure, will be _______ eV.
(Given: Planckâ€™s constant (h) = 6.63 Ã— 10^{34} Js, electron charge e = 1.6 Ã— 10^{19} C)

23) A submarine (A) travelling at 18 km/hr is being chased along the line of its velocity by another submarine (B) travelling at 27 km/hr. B sends a sonar signal of 500 Hz to detect A and receives a reflected sound of frequency Î½. The value of v is close to ________ Hz.
(Speed of sound in water = 1500 ms^{1})

24) The reading of the ammeter (in mA) for a silicon diode in the given circuit is

25) A convex lens (of focal length 20 cm) and a concave mirror, having their principal axes along the same lines, are kept 80 cm apart from each other. The concave mirror is to the right of the convex lens. When an object is kept at a distance of 30 cm to the left of the convex lens, its image remains at same position even if the concave mirror, by itself would produce a virtual image would be _______ cm.

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1) The group number, number of valence electrons and valency of an element with atomic number 15, respectively, are:

15, 5 and 3

15, 6 and 2

16, 5 and 2

16, 6 and 3


2) The correct match between ItemI and ItemII is:

a â†’ r, b â†’ p, c â†’ s, d â†’ q

a â†’ q, b â†’ s, c â†’ p, d â†’ r

a â†’ r, b â†’ s, c â†’ p, d â†’ q

a â†’ q, b â†’ p, c â†’ s, d â†’ r


3) Consider the reversible isothermal expansion of an ideal gas in closed system at two different temperatures T_{1} & T_{2 }(T_{1} < T_{2}). The correct graphical depiction of the dependence of work done (w) on the final volume (v).


4) The increasing order of the pK_{b} of the following compound is:
(A)Â Â
Â
(B)Â Â
(C)Â Â Â Â
(D)Â Â Â Â

(c) < (a) < (d) < (b)

(b) < (d) < (a) < (c)

(a) < (c) < (d) < (b)

(b) < (d) < (c) < (a)


5) Which of the following tests cannot be used for identifying amino acids?

Biuret test

Barfoed test

Ninhydrin test

Xanthoproteic test


6) The difference in the number of unpaired electrons of a metal ion in its highspin and lowspin octahedral complexes is two. The metal ion is:

Ni^{2+}

Fe^{2+}

Co^{2+}

Mn^{2+}


7) NaH is an example of :

electron rich hydride

metallic hydride

saline hydride

molecular hydride


8) Peroxyacetyl nitrate (PAN), an eye irritant is produced by:

classical smog

acid rain

organic waste

photochemical smog


9) Two blocks of the same metal having same mass and at temperature T_{1} and T_{2} respectively, are brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The change in entropy, Î”S, for this process is:


10) Which of the following compounds will be suitable for Kjeldahlâ€˜s method for nitrogen estimation?


11) Given:
Â Â i.Â Â Â Â Â Â Â Â C_{(graphite)}+O_{2(g)} â†’ CO_{2(g)}; âˆ†rHÂ°= x kJ mol^{1}
Â ii.Â Â Â Â Â Â Â Â C_{(graphite)}+ O_{2(g) }â†’ CO_{(g)}; âˆ†rHÂ° = y kJ mol^{1}
iii.Â Â Â Â Â Â Â Â CO_{(g)}+ O_{2(g) }â†’ CO_{2(g)}; âˆ†rHÂ°= z kJ mol^{1}
Based on the above thermochemical equations, find out which one of the following algebraic relationships is correct?

x = y + z

z = x â€“ y

y = 2z â€“x

x = y â€“ z


12) The major product of the following reaction is:

CH_{3}CH = C = CH_{2}


CH_{3} CH=CHCH_{2}NH_{2}

CH _{3}CH_{2 }C â‰¡ CH


13) The statement that is INCORRECT about the interstitial compound is:

they have metallic conductivity

they have high melting points

they are chemically reactive

they are very hard


14) The IUPAC symbol for the element with atomic number 119 would be:

Uun

Uue

Unh

Une


15) Polysubsititution is a major drawback in:

Friedel Craftâ€™s alkyation

Reimer Tiemann reaction

Acetylation of aniline

Friedel Craftâ€™s acylation


16) Liquid â€˜Mâ€™ and liquid â€˜Nâ€™ form an ideal solution. The vapour pressures of pure liquids â€˜Mâ€™ and â€˜Nâ€™ are 450 and 700 mm Hg, respectively at the same temperature. Then correct statement is:
(x_{M} = mole fraction of â€˜Mâ€™ in solution; x_{N} = mole fraction of â€˜Nâ€™ in solution;
y_{m} = mole fraction of â€˜Mâ€™ in vapour phase; y_{N} = mole fraction of â€˜Mâ€™ in vapour phase)



(x_{M}y_{M}) < (x_{N}y_{N})



17) The element having greatest difference between its first and second ionisation energies, is

Ca

K

Ba

Sc


18) Match the catalysis (Column â€“ I) with products (Column â€“II)

(a)(iii); (b)(iv); (c)(i); (d)(ii)

(a)(iv); (b)(iii); (c)(ii); (d)(i)

(a)(ii); (b)(iii); (c)(i); (d)(iv)

(a)(iii); (b)(i); (c)(ii); (d)(iv)


19) The INCORRECT statement is:

The spinonly magnetic moments of [Fe(H_{2}O)_{6}]^{2+ }and [Cr(H_{2}O)_{6}]^{2+ }are nearly similar.

the spinonly magnetic moment of [Ni(NH_{3})_{4}(H_{2}O)_{2}]^{2+} is 2.83 BM.

The gemstone, ruby, has Cr^{3+ }ions occupying the octahedral sites of beryl.

the color of [CoCl(NH_{3})_{5}]^{2+} is violet as it absorbs the yellow light


20) Which one of the following graphs between molar conductivity (Ë„_{m}) versus Â is correct?


21) The highest value of the calculate spinonly magnetic moment (in BM) among all the transition metal complexes is

22) The ground state energy of hydrogen atom is 13.6 eV. The energy of second excited state of He^{+ }ion in eV is:

23) for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm^{2} mol^{1}, respectively. If the conductivity of 0.001 MHA is 5 10^{5}S cm^{1}, degree of dissociation of HA is:

24) The number of pentagons in C_{60} and trigons (triangles) in white phosphorus, respectively, are 12 and _____

25) The basic structural unit of feldspar, zeolites, mica, and asbestos is (SiO_{4})^{x} hence x is

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1) Let. If the eccentricity of the hyperbola Â is greater than 2, then the length of its latus rectum lies in the interval:

(3, âˆž)





2) If Î¸ denotes the acute angle between the curves, y = 10  x^{2 }Â Â and y = 2 + x^{2} at a point of their intersection, then tan Î¸ is equal to:


3) Two cards are drawn successively with replacement from a well shuffled deck of 52 cards. Let X denote the random variable of number of aces obtained in the two drawn cards. Then P(X = 1) + P(X = 2) equals


4) Two sides of a parallelogram are along the lines, x + y = 3 and x â€“ y + 3 = 0. If its diagonals intersect at (2, 4), then one of its vertex is:

(3, 5)

(2, 1)

(2, 6)

(3, 6)


5) Let f be a differential function such that

exists and equals

exists and equals 4

does not exist

exists and equals 0


6) On which of the following lines lies the point of intersection of the line,
and the plane, x + y + z = 2?


7) Two integers are selected at random from the test set {1, 2, â€¦ , 11}. Given that the sum of selected numbers is even, the conditional probability that both the numbers are even is:


8) If for a suitable chosen integer m and a function A (x), where C is a constant of integration, then (A(x))^{m} equals:


9) Let. If AA^{T} = I_{3}, then p is:


10) The integral log_{e} x dx is equal to:


11) The equation of a tangent to the parabola, x^{2 }= 8y, which makes an angle Î¸ with the positive direction of Xaxis, is:

y = x tan Î¸ + 2 cot Î¸

y = x tan Î¸ â€“ 2 cot Î¸

x = y cot Î¸ + 2 tan Î¸

x = y cot Î¸ â€“ 2 tan Î¸


12) The number of integral values of m for which the quadratic expression, (1+2m)x^{2 }2(1 + 3m)x + 4 (1 + m), x â‹´ R, is always positive, is:

3

8

7

6


13) A student score the following marks in five tests: 45, 54, 41, 57, 43. His score is not known for the sixth test. If the mean score is 48 in the six tests, then the standard deviation of the marks in six tests is:


14) The vector equation of the plane through the line of intersection of the planes x + y + z = 1 and 2x + 3y + 4z = 5 which is perpendicular to the plane x â€“ y + z = 0 is:


15) The height of a right circular cylinder of maximum volume inscribed in a sphere of radius 3 is:


16) Let p, q Ïµ R, if Â is a root of the quadratic equation, x^{2} + px + q = 0, then:

q^{2} + 4p + 14 = 0

p^{2} â€“ 4q + 12 = 0

p^{2}  4q  12 = 0

q^{2}  4p  16 = 0


17) If then the inverse of is:


18) Let S be the set of all values of x for which the tangent to the curve y = f (x) = x^{3} â€“ x^{2} â€“ 2x at (x, y) is parallel to the line segment joining the points (1, f (1)) and (1, f (1)), then S is equal to:


19) Let f(x) = log_{e} (sin x), (0 < x < Ï€) and g(x) = sin^{1}(e^{x}), (xâ‰¥0)If Î± is a positive real number such that a = (fog)â€™(Î±) and b = (fog)(Î±), then

aÎ±^{2 }+ bÎ± â€“ a = 2Î±^{2}

aÎ±^{2 }â€“ bÎ± â€“ a = 0

aÎ±^{2 }â€“ bÎ± â€“ a = 1

aÎ±^{2 }+ bÎ± + a = 0


20) A perpendicular is drawn from a point on the line Â Â to the plane x + y + z = 3 such that the foot of the perpendicular Q also lies on the plane x â€“ y + z = 3. Then the coordinates of Q are

(2, 0, 1)

(1, 0, 4)

(1, 0, 2)

(4, 0, 1)


21) Minimum number of times a fair coin must be tossed so that the probability of getting at least one head is more than 99% is equal to __________.

22) The equation, represents the line through the origin with slope _____________.

23) If the normal to the ellipse 3x^{2} + 4y^{2} = 12 at a point P on it is parallel to the line, 2x + y = 4 and the tangent to the ellipse at P passes through Q(4, 4) such that PQ = then m is equal to ________.

24) If, then –2mn is equal to :

25) L_{1} is the line of intersection of the planes 2x – 2y + 3z – 2 = 0, x – y + z + 1 = 0 and L_{2} is the line of intersection of the planes x + 2y – z – 3 = 0, 3x – y + 2z – 1 = 0. If the distance of the origin from the plane, containing the lines L_{1} and L_{2}, is then ‘a’ is equal to _______.

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