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Class 12-science H C VERMA Solutions Physics Chapter 5 - Specific Heat Capacities of Gases

Specific Heat Capacities of Gases Exercise 77

Solution 1

Mechanical energy is converted into internal energy. Thus,

  

  

  

Solution 2

We know,

dQ=dU+dW

dQ=dU (As dW=0)

  

  

Q=8.6cal

Or Q=36.12J

Solution 3

We know,

dW=PdV

  

  

dW=300J

Also, dW=nRdt

  

And   

  

  

dQ=1050J

Solution 4

We know,

  

So

  

  

Also,

  

  

  

Solution 5

a) We know,

dQ=dU+dW

dU=dQ-dU

  

  

  

=6RdT

  

dU=2490J

b) dU=dQ

  

  

  

dU=2490J

c) Adiabatically   

  

  

  

  

dU=2490J

Specific Heat Capacities of Gases Exercise 78

Solution 6

We know,

PV = nRT

  

  

  

Also,

  

  

  

Also,

  

  

=51.18

  

  

=2.08cal

Solution 7

a) We know,

dQ=dU+dW

dU=dQ-dW

=dQ-PdV

  

dU=30J

b) For monoatomic gas

  

  

n=0.008

c) We know,

  

  

  

And   

=12.5+8.3=20.3

d) From equation 1

  

Solution 8

We know,

  

  

  

  

Also,

  

  

Q=3nRT

Or

  

  

Solution 9

As given:

P=kV

  

  

RdT=2kVdV

  

We know,

dQ=dU+dW

  

  

  

  

Solution 10

As given

  

  

  

  

  

  

Solution 11

For   ideal gas:

  

For   ideal gas:

  

As given   

i.e.   

  

When we mix the gas

  

  

  

  

  

Also, 

  

Taking ratio of equation 1 and 2

  

Solution 12

We know,

  

  

  

  

Also,

  

  

Ratio   

  

Solution 13

a) We know,

  

  

  

  

b) We know,

  

  

  

=1250J

Also, dQ=dU+dW [[For bc process, dW=0]

  

  

  

  

c) Heat liberated,   

  

  

=750J

d) Also, Heat libeated,  (for cd process)

  

  

=2500J

Solution 14

a) In case of ab ,   is constant

Thus,   

  

  

In case of bc, Pis constant

Thus   

  

  

 

b) Work done=Area under graph

  

c) We know,

  

  

  

Q=14.9J

And also,

  

  

  

Q=24.9J

d) We know,

  

  

=(24.9+14.9)-1 [from1 and 2]

  

Solution 15

We know

  

  

  

Solution 16

a) We know

  

  

  

b) We know,

  

  

  

  

Solution 17

a)   

  

  

  

b)

  

  

  

  

c) Workdone is given as:

  

  

W=21J

Solution 18

A diabetic process

Thus,

  

  

  

  

  

Solution 19

a) We know

  

  

  

  

Also,

  

  

  

b) When the container is slowly compressed then also heat transferred is 0 because walls are adiabatic and thus

Pressure p=800kPa

And temperature T=600K

Solution 20

a) First slowly compressed Isothermal compression.

So,

  

  

Now, suddenly compressed Adiabatic compression.

  

  

  

  

b) First gas is compressed suddenly Adiabatic compressin

  

  

  

  

Now, gas is compressed slowly Isothermal compression.

  

  

  

Solution 21

a) Isothermal condition

  

  

  

Now, adiabatic condition. Thus,

  

  

  

b) Adiabatic condition:

  

  

Now, isothermal condition,

  

  

Solution 22

a) We know,

PV=nRT

  

n=0.009moles

b) We know,

  

  

  

c) Adiabatic process  

  

  

  

Or

  

d) We know,

  

  

  

W=-33J

e) We know, internal energy

  

  

W=33J

Specific Heat Capacities of Gases Exercise 79

Solution 23

A is isothermal, Thus.

  

  

  

B is adiabatic. Thus,

  

  

  

C is isobaric process. Thus,

  

  

And   

As given

  

  

Ratio is given as:

  

  

Solution 24

Work done is given as:

  

And  

As work done is equal for both cases, Thus,

  

  

Also we know,

  

  

Substituting above equation in 3 we get

  

  

Solution 25

a) Adiabatic process, Thus,

  

  

  

b) We know,

  

  

  

And also

  

  

  

Now

  

  

  

c) We know,

dQ=dU+dW

dU=-dW [As dQ=0]

dU=+82J

d) from equation 1

  

  

e) Isobaric process as pressure is constant. Thus,

  

  

f) Here,   

  

  

For isothermal condition,

  

  

  

g) Net work done,   

=-82-41.4+103

=-20.4J

Solution 26

In this, adiabatic process is going on. So

  

 

  

 

So,   

  

Solution 27

a) We know,

PV=nRT

  

n=0.008

b) We know,

dQ=dU+dW

dQ=dU (dW=0,as no change in volume)

  

  

For A,

  

And   

  

  

For B,

  

And   

  

  

Distance moved by mercury =  

=25-12.5

  

Solution 28

Adiabatic process, Thus.

For  ,   

  

For  ,   

  

Where m is mass of H2

Equating 1 and 2 we get,

  

m=0.029

m=0.03g

Solution 29

a) Temperature remains constant as A is diathermic

Thus,   

  

  

And   

Now as B is adiabatic,

  

  

Solving we get

  

Also,

  

  

  

  

b) Here, temperature remains constant because value is open.

  

And

  

A is diathermic thus, T and V are constant and so pressure also remains constant.

  

B is adiabatic. Thus,

  

  

Or   

Solution 30

a) Adiabatic process,

  

And

  

 

  

 

  

When equilibrium is reached then

 

  

  

Solving we get

  

And

  

b) Process is adiabatic so no heat is transferred to left part.

Q=0

c) From equation 1

  

And from equation 3

  

Thus, equation 5 becomes:

  

  

Solution 31

Process is adiabatic. Thus,

  

  

  

  

Also,

  

V=447m/s

Specific Heat Capacities of Gases Exercise 80

Solution 32

We know,

Spedd of sound,   

  

  

Also,

  

=18.0J/mol-x

Also,

  

  

=26.3J/mol-K

Solution 33

We know,

  

  

  

Also, speed od sound V=  

  

V=960m/s

Solution 34

In kundt's tube, node separation is given as:

  

  

Speed of sound   

  

=360m/s

Also,

  

Thus,

  

  

Now, we know,

  

  

Also,

  

  

  

Solution 35

Speed of sound   

  

=330m/s

Also,

  

{PV=nRT

 }

  

So,   

  

  

We know,

  

  

And

  

  

  

  

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