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Class 12-science H C VERMA Solutions Physics Chapter 2: Kinetic Theory of Gases

Kinetic Theory of Gases Exercise 34

Solution 1

 Pa

n=1 mol

T=273 K

R=8.3 J/mol-K

PV=nRT

  

  

  

Solution 2

 Pa;  ; T=273 K; R=8.3 J/mol-K

PV=nRT

PV=  

N=  

=  

  

Solution 3

  

  

 Pa

  

T=273 K

  

  

  

  

  

Solution 4

At STP, 22.4 ltr. of oxygen contains 32gm of oxygen.

  

  

  

 gm

  mg 

Solution 5

 

Since mass is same,

  

Ideal gas equation

PV=nRT

  

  

  

Solution 6

PV=nRT

  

  

  

  

  

Solution 7

Ideal gas equation:

PV=nRT

P T

  

  

 375 K 

Solution 8

 mol

PV=nRT

  

 Pa 

Solution 9

  

  

  

  

Solution 10

  

  

  

  

 0.987

Solution 11

Initially,

  

So,   

Now,

  (diathermic separator)

  

  

Since,   

  

  

Solution 12

  

  

  m/s

  m/s

Now,

  

  

  

 1200 K

Solution 13

  

  

  

  

  

 =1300 m/s 

Solution 14

  

  

 310K  

Solution 15

  

 445.25 m/s

We know,

  

 [R=6400 km]

  sec

  

  

Solution 16

  

  

 1201.35 m/s

Momentum=m  

=  

=  

 Kg-m/s 

Solution 17

  

  

  

  

  

Solution 18

 

  

  

  

 11800 K 

Kinetic Theory of Gases Exercise 35

Solution 19

  

  

  

Solution 20

  

  

  

 1.18 

Solution 21

  

  

=1687 m/s

  

Time between two collisions= sec

Number of collision in 1 sec=  

Solution 22

(a)  

  

=1781 m/s

 1780 m/s

 

(b)

 

 

Change in momentum of molecule=mv  (mv )

  =  mv

Total DP for N molecules=  

  

   Mass of a molecule         Kg So,   

Solution 23

  

  

PV=nRT

  

  

  

Solution 24

Initially,

  

  

  

  

  

  

  

Now

  

  

  

  

  

  

  

Mass of gas leaked=  

= 1.446-1.285

= 0.16 gm 

Solution 25

Since temperature and number of moles are constant.

  

  

  

  

  

Solution 26

Initially,

  atm;   

  

  

  

Now,

  

  

  

  

No. of moles leaked=  

=0.16-0.02

=0.14 

Solution 27

  

  

  

T-100=96.38

T=196.38  

T196  

Solution 28

 =constant

 =constant

TV=constant

  

  

  

Solution 29

  

  

 2250 Pa 

Solution 30

 

No of moles initially=No of moles finally [ Container is closed]

  

  

  

  

  

h=0.25 m

h=25 cm 

Solution 31

No. of moles initially= No. of moles finally

  

  

Solution 32

(a)   

  

  

  

  

 

(b)   

  

  

  

 

(c)   

  

  

P73.16 kPa

P73 kPa

Solution 33

 

No. of moles initially=No. of moles finally

  

  

  

h=15.3 cm

h15 cm 

Solution 34

 

No of moles in left side=No of moles in Right side

[Initially P,V,R,Tis same on both sides.]

Now,

  

  

  

400l=273(90-l)

673l=273×90

l=36.5 cm  

Solution 35

 

 cm of Hg

 cm of Hg

 cm of Hg

 cm of Hg

No. of moles initially=No. of moles finally

  

  

l=48 cm 

Kinetic Theory of Gases Exercise 36

Solution 36

 

Initially,

  

By ideal gas equation

  

  

divide

  

  - (i)

Now,

 

 

By ideal gas equation,

  

  

divide

 (ii)

From (i) and (ii)

  

  

 from left end.

Solution 37

Let at any time t, pressure and no. of moles be P and n respectively.

So,   

In dt time, dn moles are taken out and pressure decreases by dP.

  

  

  -(i)

The pressure of gas taken out is equal to the inner pressure.

  

  

  -(ii) [Here dP.dV 0]

From (i) and (ii)

  

  

  

  

  

  

 

(b) When half gas is leaked out, pressure will become half of initial.

  

So,   

  

  

  

Taking in on both the sides.

  

  

Solution 38

  

  [Using PV=nRT]

Now,   

  [Here n=1]

  

Solution 39

Internal energy=  

  

Since pressure P is constant and V=Volume of room is also constant.

So, U=Constant. 

Solution 40

No. of moles at 300 K=No. of moles at 600 K(just before cork comes out)

  

  

 Pascal

Net force on cork by gas and atmosphere at 600 K=  

  

 Newton

Just before cork comes out

  

  

  

Now,

  

Solution 41

(a) The pressure outside and inside is same,

So, net pressure is zero on the pistons.

So, Tension=0

 

(b)

 

  

  

  

Net force on piston is zero

  

  

Solution 42

 

(a)   

  

  

  

(b) Applying Bernoulli's at A and C

  

  

  

 

(c) If water stops coming out then pressure on horizontal line passing through hole will be  . So, in long vertical no water must be present above this line as it is open to atmosphere. Height of water in long tube above the top is   

Solution 43

No. of moles initially=No. of moles finally

  

  

  

l=2.2m 

Solution 44

No. of moles initially=No. of moles finally

  

  

 cm

Solution 45

  

  

Here ,   

  

P=84 cm of Hg

Kinetic Theory of Gases Exercise 37

Solution 46

Temperature is 20  and relative humidity is 100%, So air is in saturated condition.

Dew point is the temperature at which SVP is equal to present vapour pressure.

So, 20  is the dew point. 

Solution 47

  

  

 Pa

When vapours are removed VP reduces to zero.

Net pressure inside the room now=  

=  KPa

102 KPa

Solution 48

Air becomes saturated at 10 .

If room temperature falls to 15 then also dew point=10 .

Solution 49

  

The point where the vapor starts, condensing VP=SVP.

Since, the process is isothermal.

  

  

  

  

  

Solution 50

 76 cm of Hg

Now, when water is introduced the water vapor exerts some pressure against atmospheric pressure.

Pressure of vapor=76-75.4

=0.6 cm of Hg

  

Solution 51

At pressure of 760 mm we drop perpendicular on temperature axis, So, T=65  

Similarly, at 0.5 atm, T=48  

Solution 52

Temperature of body=  

=  

=36.7  

From graph, pressure corresponding to temperature 36.7  is 50 mm of Hg. 

Solution 53

Dew point=10  

At 20 , SVP=17.5 mm of Hg

At 10  (dew point), SVP=8.9 mm of Hg

  

  

=51% 

Solution 54

At 30 ,   of air contains 30 gm of water vapour

In   air, water vapour=  

=1500 gm

At 20,   of air contains 16 gm of water vapour

In   air, water vapour=  

=800 gm

Amount of water vapour condensed=1500-800=700 gm 

Solution 55

 76 cm of Hg

SVP=0.8 cm of Hg

When water is introduced into the barometer, water evaporates and exerts pressure on mercury meniscas.

Pressure is minimum when the vapour reaches at saturation.

Net length of Hg column at SVG=76-0.8

=75.2 cm 

Solution 56

Pressure exerted by   vapour= V.P

=99.4KPa-3.4KPa

=96kPa

Using, PV=nRT

96×  

  

  

Solution 57

Let length of barometer tube be x

Initially,

  

  

 1 cm of Hg

Later

  

  

 0.9 cm of Hg

Now,

  

  

  

X=91.1 cm

Solution 58

  

At 0 ,

  

 1.84 mm of Hg

Using PV=nRT;

  

  

 1.97

  

  

RH=10.9%

Solution 59

  

  

VP=1800 Pa

Extra pressure required for saturation=3600-1800=1800 Pa

Let mass of vapour required be m for extra pressure

  

  

m=13 gm 

Solution 60

  

  

VP=660 Pa

Now,

PV=nRT

  

m=238.5 gm

m238 gm 

Solution 61

  

  

VP=660 Pa

Pressure for evaporated water is given by

  

  

 1385 Pa

Net pressure=VP+  

=660+1385

=2045 Pa

  

= 61.9% 

R.H62%  

Solution 62

(a)   

  

VP=0.64 kPa

Evaporation occurs as long as the atmosphere is not saturated.

Net pressure change= (1.6-0.64) kPa

= 0.96 kPa

Let mass of water evaporated be m. Then,

PV=nRT

  

m=361.45 gm

m361 gm

 

(b) At 20 , SVP=2.4 KPa

At 15 , SVP=1.6 KPa

Net pressure change=2.4-1.6=0.8 KPa

Mass of water evaporated

PV=  

  

m=296 gm