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Sir, please solve this qustion.

 

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Asked by rsudipto 28th November 2018, 5:26 PM
Answered by Expert
Answer:
Statement ii is correct following reaction occurs in estimation process -
 
Cr2O72- + 6 Fe2+ + 14H+ → 2Cr3+ + 6 Fe3+ + 7H2O
 
statement i is false since following reaction occurs in basic medium -
 
MnO4¯ + e- → MnO42- 
 
So Equivalent weight of Mn = Atomic mass/1 (since one electron trnsaction is done in the process)
 
statement iii is also correct following reaction takes place -
 
Cr2O72- + 14H+ + 6e- → 2Cr3+ + 7H2O so N = M/6
 

(NH4)2CrO4 = Cr2O3 + NH3 + N2 + H2O

so, statement iv is also correct.

 
Answered by Expert 1st December 2018, 2:12 AM
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