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sir please answer

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Asked by minipkda 12th June 2018, 10:44 PM
Answered by Expert
Answer:
van der walls equation of state is given as
begin mathsize 12px style open parentheses p plus fraction numerator a space n squared over denominator V squared end fraction close parentheses space open parentheses V minus n b close parentheses space equals space R T space........................... left parenthesis 1 right parenthesis
end style
where a is pressure correction and b is Volume correction. n is  numver of moles.
 
Let us expand eqn.(1) and substitute n=1 as per given question
 
begin mathsize 12px style p V space plus space a over V space minus space b p space minus space fraction numerator a space b over denominator V squared end fraction space equals space R T
fraction numerator p V over denominator R T end fraction space equals space 1 space plus space b p space space..................... left parenthesis 2 right parenthesis
left parenthesis t h e space c o r r e c t i o n space t e r m s space a over V space a n d space fraction numerator a space b over denominator V squared end fraction space a r e space n e g l i g i b l e space t e r m s right parenthesis
end style
 
as per eqn.(2) plot pV/(RT) as a function of p is linear graph as shown in option (2) in the list of options.
Answered by Expert 15th June 2018, 2:32 PM
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