Which d orbitals are involved in sp3d2 and d2sp3 hybridization respectively ?
Asked by anirbanbag81
3rd January 2018,
5:54 PM
Answered by Expert
Answer:
sp3d2 or d2sp3 are hybridisation for the octahedral geometry.
In octahedron, the bonds are formed parallel to the x, y, and z-axes, hence dx2-dy2 and dz2 will be used to form the hybrid orbitals.
|
Coordination number |
Type of hybridization |
Distribution of hybrid orbitals in space |
Types of d orbitals |
|
4 |
sp3 |
Tetrahedral |
|
|
4 |
dsp2 |
Square planar |
dx2-y2 |
|
5 |
sp3d |
Trigonal bipyramidal |
dz2 |
|
6 |
sp3d2 (nd orbitals are involved; outer orbital complex or high-spin or spin-free complex) |
Octahedral |
dx2-dy2 and dz2 |
|
6 |
d2sp3 [(n − 1)d orbitals are involved; inner orbital complex or low-spin or spin-paired complex] |
Octahedral |
dx2-dy2 and dz2 |
Answered by Expert
4th January 2018,
10:17 AM
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