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CBSE Class 12-science Answered

The vapor pressure of water is 12300 Pa at 27 C. Calculate the vapor pressure of 0.5 M solution of a non dissociating/non associating solute in it.
Asked by lekhakarthikeyan | 28 Aug, 2018, 06:29: AM
answered-by-expert Expert Answer
Given:
 
Vapour pressure of H2O p01 =12300 kPa
 
                                   =12.3 Pa
 
Molality of solution =0.5 m
 
Vapour pressure of solution =p1
 
1 molal solution means 1 mole of solute in 1000 g of solvent
 
0.5 molal solution means 0.5 mole of solute in 1000 g of solvent
 
Moles space of space solvent space left parenthesis straight H subscript 2 straight O right parenthesis space equals 1000 over 18

space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals 55.56

Moles space of space solvent space left parenthesis straight H subscript 2 straight O right parenthesis space equals 55.56

Mole space fraction space of space solute space straight X subscript 2 space end subscript space equals space open parentheses fraction numerator straight o.5 over denominator 0.5 plus 55.56 end fraction close parentheses

space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space space equals 0.00891

fraction numerator straight P to the power of blank subscript 1 minus straight P subscript 1 over denominator straight P to the power of blank subscript 1 end fraction space equals straight X subscript 2 space end subscript

fraction numerator 12.3 minus straight P subscript 1 over denominator 12.3 end fraction space equals space 0.00891

straight P subscript 1 space equals space 12.3 minus straight o.1097

space space space space space equals space 12.19 space kPa
Vapour pressure of solution is 12.19 kPa
 
Answered by Varsha | 28 Aug, 2018, 02:18: PM
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