What is ionisation isomerism? Give example.
Asked by Topperlearning User | 15th Apr, 2014, 08:37: AM
Compounds which gives different ions in solution although they have same composition are called ionisation isomerism.
This form of isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion.
An example is provided by the ionisation isomers [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4.
Another example is, [Pt(NH3)4(OH)2]SO4 and [Pt(NH3)4SO4](OH)2.
Answered by | 15th Apr, 2014, 10:37: AM
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