Explain the preparation of Potassium pemanganate ?

Asked by Abhijith C | 11th Nov, 2012, 05:29: AM

Expert Answer:

When manganese dioxide is fused with potassium hydroxide in the presence of air or an oxidising agent such as potassium nitrate or chlorate, potassium manganate is formed, possibly via potassium manganite.
 
                                                  fused
            MnO2 + 2KOH ––––––?    K2MnO3          +    4H2O] × 2
                                                              potassium manganite
            2K2MnO3 + O2 ––––––? 2K2MnO4 + 2H2O
                                                             fused
            2MnO2 + 4KOH + O2 ––––––? 2K2MnO4 + 2H2O
            pyrolusite                                     potassium manganate

Answered by  | 12th Nov, 2012, 01:26: PM

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