An organic compound A on treatmentr with acetic acid in presence of conc H2SO4 produce sester B .A on mild oxidation gives C. C reacts with 50% KOH followed by acidification generates A and D .D with PCl5 followed by reation with NH3 gives E . E on dehydration produces HCN .I dentify the compound A to E AND WRITE THE CHEMICAL REACTION.
Asked by vasturushi | 23rd Jul, 2017, 11:07: AM
Answered by Vaibhav Chavan | 24th Jul, 2017, 11:10: AM
- sir/madam, this doubt will be lenghty. request peace reading. the doubt is w.r.t chapter Amines; to be specific it is w.r.t basicity of amines. in the topic of the comparision of the basic character of alkylamines with ammonia, the order of basicity of amines is tertiary> secondary> primary in gaseous phase, only due to the +I effect. in gasous phase only +I effect is shown? also in the aqueous phase, the disturbancy in the order of basicity is due to the sum of effects of +I effect, solvation effect and steric hindrance? the order of the stability of the following in aqueous phase: +I effect: tertiary> secondary> primary solvation: primary > secondary > tertiary steric hindrance: primary > secondary > tertiary so does it means that +I is effected in both gaseous and aqueous phase but solvation and steric hindrance are effected only in aqueous phase? also sir there is an order of basicity when R= CH3 group and when R= C2H5 group: R= CH3: secondary> primary> tertiary R= C2H5: secondary> tertiary> primary so sir can we generalise the order that: when R=CH3 group, the order of basicity: secondary> primary> tertiary and when R> CH3 group, the order of basicity: secondary> tertiary> primary
- sir/ madam, is it true that if no of bonds in an atom increases then the atom acquires a positive charge on it and when it loses one bond it acquires a negative charge on it ? why does it happen so?
- pls explain
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